Unit 3: Atmosphere


1. Definition, Composition, and Importance

Definition: Atmosphere

The Atmosphere is the thin envelope of gases that surrounds the Earth, held in place by gravity.

Composition

The atmosphere is a mixture of gases. The composition of dry air is:

Importance of Atmosphere

  1. Provides Gases for Life: It contains the oxygen (O₂) we breathe and the carbon dioxide (CO₂) plants use for photosynthesis.
  2. Filters Harmful Radiation: The ozone layer in the stratosphere blocks most of the sun's harmful ultraviolet (UV-B and UV-C) radiation.
  3. Regulates Temperature (Greenhouse Effect): It traps heat from the sun, keeping the planet warm enough for life to exist. Without it, Earth's average temperature would be about -18°C.
  4. Weather and Water Cycle: It is the medium for the hydrological (water) cycle, creating weather, clouds, and rain.
  5. Protection from Meteors: It acts as a shield, burning up most meteoroids before they can strike the surface.

2. Layers of Atmosphere

The atmosphere is divided into layers based on how temperature changes with altitude.

Diagram: A vertical graph. X-axis = Temperature. Y-axis = Altitude (km).
1. Troposphere (0-12 km): Temp decreases with altitude. (Weather layer)
2. Stratosphere (12-50 km): Temp increases with altitude. (Ozone layer)
3. Mesosphere (50-80 km): Temp decreases with altitude. (Meteors burn up)
4. Thermosphere (80+ km): Temp increases with altitude. (Auroras)
  1. Troposphere (0 - ~12 km):
    • The lowest layer, where we live.
    • Temperature decreases as you go up (it's heated from the ground up).
    • Contains ~80% of the atmosphere's mass and almost all of the water vapor.
    • This is where all weather (clouds, rain, wind) occurs.
  2. Stratosphere (~12 - 50 km):
    • Temperature increases as you go up.
    • This warming is because the Ozone Layer is in this layer, and it absorbs UV radiation from the sun.
    • This layer is very stable (no weather), which is why airplanes prefer to fly here.
  3. Mesosphere (~50 - 80 km):
    • Temperature decreases again, reaching the coldest temperatures in the atmosphere (around -90°C).
    • This is where most meteors ("shooting stars") burn up from friction.
  4. Thermosphere (~80+ km):
    • Temperature increases dramatically (to >1000°C) due to absorption of high-energy solar radiation.
    • The air is extremely thin.
    • This is where auroras (Northern/Southern Lights) occur and where many satellites orbit.

3. Stratospheric Ozone (The "Good" Ozone)

Ozone (O₃) is a molecule made of three oxygen atoms. It's important to know there are two types:

The Ozone Layer is a region in the stratosphere (approx. 15-30 km high) with a relatively high concentration of ozone. Its job is to act as a global sunscreen, absorbing 97-99% of the sun's harmful ultraviolet (UV) radiation, especially UV-B and UV-C, preventing it from reaching the surface.


4. Depletion of Ozone Layer and Ozone Hole

The Problem: Depletion

In the 1970s and 1980s, scientists discovered that the ozone layer was thinning globally, with a severe seasonal depletion over Antarctica, known as the "Ozone Hole."

The Cause: CFCs

The primary culprits were a class of chemicals called Chlorofluorocarbons (CFCs). These were widely used as refrigerants (e.g., in air conditioners, refrigerators), in aerosol spray cans, and as industrial solvents.

The Chemical Process:

  1. CFCs are very stable, so they are not destroyed in the troposphere. They slowly rise to the stratosphere.
  2. In the stratosphere, high-energy UV radiation breaks the CFC molecule apart, releasing a chlorine (Cl) atom.
  3. This chlorine atom acts as a catalyst, starting a destructive chain reaction.
    Cl + O₃ → ClO + O₂ (Chlorine destroys an ozone molecule)
    ClO + O → Cl + O₂ (The chlorine atom is regenerated, free to destroy another ozone)
  4. A single chlorine atom can destroy up to 100,000 ozone molecules before it is finally removed from the atmosphere.

Consequences of Depletion:

With less ozone, more UV-B radiation reaches the surface, causing:

The Solution: The Montreal Protocol (1987)

In a major international success story, the world's nations signed the Montreal Protocol, an agreement to phase out the production and use of CFCs and other ozone-depleting substances. This protocol has been highly effective, and the ozone layer is now slowly beginning to recover.


5. Global Warming and Climate Change

The Greenhouse Effect (Natural vs. Enhanced)

Global Warming vs. Climate Change

Consequences of Climate Change:


6. Acid Rain

Definition

Acid rain is any form of precipitation (rain, snow, fog, or dry particles) that is unusually acidic, meaning it has a pH lower than normal rain (which is ~5.6). Acid rain can have a pH of 4.2 or even lower.

The Cause

The main cause is the burning of fossil fuels, especially coal (for electricity) and oil (in vehicles).

  1. Burning these fuels releases Sulphur Dioxide (SO₂) and Nitrogen Oxides (NOₓ) into the atmosphere.
  2. These gases react with water, oxygen, and other substances in the atmosphere to form Sulphuric Acid (H₂SO₄) and Nitric Acid (HNO₃).
  3. These strong acids dissolve in water droplets and fall to the Earth as acid rain.

Consequences of Acid Rain: